copper phthalocyanine solubility

The density is 1.94~2.05g/cm3. The discovery of metal phthalocyanines can be traced to the observation of intensely colored byproducts from reactions of phthalic acid (benzene-1,2-dicarboxylic acid) or its derivatives with sources of nitrogen and metals. Epub 2017 Apr 28. help you have the best experience while on the site. Visit our privacy RH conditions were controlled by injecting water vapor into the vacuum chamber using a mass flow controller at 20cm3/min flow rate. Please Contact Us Registered Trademark. By visiting this website, certain cookies have already been set, which you may delete and block. BODIPY is thermodynamically not feasible, the singlet ZnPc decayed to populates the triplet ZnPc, in addition to the grounds A LabVIEW program was used to control the H2O flow and record resistivity of the film and frequency shift of the QCM during the experiment. Phase Transition of Graphene-Templated Vertical Zinc Phthalocyanine Nanopillars. The basic copper phthalocyanine has a very low solubility in water (0.009 mg/L) and in octanol (0.0004 mg/L). & Torres, T. Phthalocyanines: from outstanding electronic properties to emerging applications. Del Cano, T., Parra, V., Rodrguez-Mndez, M., Aroca, R. & De Saja, J. CAS [3] Benzene at 40C dissolves less than a milligram of H2Pc or CuPc per litre. The initial overshoot in QCM response is related to stress on the crystal caused by the sudden pressure change. MeSH The presence of pinholes and large (10100nm diameter) interstitial spaces between grains result in high film porosity and surface area which allows for rapid H2O diffusion into the bulk film. In crystals with unit cells composed of n molecules, the nondegenerate excited states of each molecule are comprised of n bands, resulting in several absorption peaks22. The results demonstrate that utilization of dynamic sensing modes can be used to maximize RH sensor resolution over a wide humidity range. Mohamed E El-Khouly, Cem Gl, Morad M. El-Hendawy, Sekan Yeilot, Mahmut Durmu. nines to grant solubility,1 in aqueous ambience in particular, e.g. Rh6d;0/YH0 EQLRYdkZLkN}ej[zb[Aa$Csa4m# X'yx#J0_BGB?Mvhd2jvHPIdX;Bw-tf4[3HLg.yKSu5M5KlL =N8 Spectrophotometric-chemometrics study of the effect of solvent composition and temperature on the spectral shape and shift of copper and nickel phthalocyanines in different aqueous-nonaqueous mixed solvents. 2d (bottom panel). 199, 324329 (2014). FOIA The Journal of Physical Chemistry B [17] The color is due to a * electronic transition, with max 610nm. The ratio of A2/A1 corresponds to the relative activity of adsorbates at site 2 relative to site 1, while 2/1 corresponds to timescale associated with the adsorption rate at site 2 relative to the adsorption rate at site 1. The average height visible in the AFM image is ~21nm, which suggests that pinholes visible in the image penetrate to a depth of at least half of the film thickness. The kinetic study of energy transfer measured by monitoring the decay of the BODIPY emission, revealed fast energy transfer (5.90 1010 s-1) in the molecular pentad. FOIA General Comments : Soluble in 98% H2SO4, stable toward heat. 156, 210 (2010). Effects of humidity on the electrical properties of thermal inkjet-printed films of copper tetrasulfonated phthalocyanine (CuTsPc) onto paper substrates. * To send your quote request for bulk quantities, please click on the "Request Quote" button. (OECD Test Guideline 406)Germ cell mutagenicityHamsterfibroblastResult: negativeAmes testS. 34, 735742 (2000). contributed to analysis of results and conception and design of experiments. This website requires certain cookies to work and uses other cookies to help you have the best experience. Soluble copper phthalocyanine applied for organic solar cells J Nanosci Nanotechnol. Integration of an M-phthalocyanine layer into solution-processed organic photovoltaic cells for improved spectral coverage. We studied the interaction of H2O vapor with film of CuPcTs using a multi-modal approach which links gravimetric, broadband dielectric spectroscopy, and DC electrical resistivity measurements. NY Times Paywall - Case Analysis with questions and their answers. Periodic table of the elements, materials science and academic information, elements and advanced materials data, scientific presentations and all pages, designs, concepts, logos, and color schemes herein are the copyrighted proprietary rights and intellectual property of American Elements. Submit a Request for Proposal (RFP) to suppliers of your choice with details on what you need with a click of a button. It is highly valued for its superior properties such as light fastness, tinting strength, covering power and resistance to the effects of alkalis and acids. doi: 10.1016/j.solmat.2011.01.042. [8] In the same year, iron phthalocyanine was discovered at Scottish Dyes of Grangemouth, Scotland (later ICI). Jarota, A., Brozek-Pluska, B., Czajkowski, W. & Abramczyk, H. Water confined in films of sulphonated phthalocyanines. However, recents trends show a reverse tendency for the baking process mainly on the grounds of economical and ecological concerns (solvent-free, shorter lead time). To prepare these complexes, the phthalocyanine synthesis is conducted in the presence of metal salts. * orbital transitions, and the B (Soret) band (~300450nm), associated with a2u to eg Sign up today! government site. 8600 Rockville Pike There are many derivatives of the parent phthalocyanine, where either carbon atoms of the macrocycle are exchanged for nitrogen atoms or the peripheral hydrogen atoms are substituted by functional groups like halogens, hydroxyl, amine, alkyl, aryl, thiol, alkoxy and nitrosyl groups. Copper(II) Phthalocyanine (-form) Basic information: Product Name: . 29, 814818 (2009). [32] Copper phthalocyanine dyes are produced by introducing solubilizing groups, such as one or more sulfonic acid functions. Pseudo-first order, pseudo-second order, and double exponential fits were used to model kinetics of H2O adsorption on CuPcTs film. Direct blue 86 is the sodium salt of CuPc-sulfonic acid, whereas direct blue 199 is the quaternary ammonium salt of the CuPc-sulfonic acid. Thin Solid Films Although ${\theta }_{2}$ calculated from the PFO model is roughly a factor of 2 larger than ${\theta }_{2}$ predicted from the double exponential model at high RH, both models predict that Site-2 occupancy increases by a factor of 34 between 10% and 95% RH. 2012 Jan;32(1):157-61. In particular, we find that mass-based measurements achieve the highest resolution at RH<50% while optical techniques achieve the highest resolution at RH>50%. A LevenbergMarquardt algorithm was used for fitting oscillator parameters. Park, J. H., Lee, S. & Kummel, A. C. Domain fracture and recovery process of metal phthalocyanine monolayers via NO2 and H2O. Solubility In Water Specific Gravity PH of % Aq. Please join us and our customer and co-sponsor. Error bars correspond to linear fitting errors. Woollam Co. M-2000 ellipsometer. A flow cell with optical windows was used to control the sample environment during SPE measurements. use 1. Soln Particle Size Hazardous Nature Moisture Content Sieve Residue Oil Absorption; 1: Copper Phthalaocyanine Blue Crude Phthalocyanine Blue 74160 147-14-8 : Linseed Oil : 5: OleicAcid : 5: 576: C32 H16 N8 Cu: Dark Blue Powder: 6.0 - 7.5: 1 %: 1000 PPM Max Moradian S, Dezhampanah H, Ghasemi JB, Behnejad H. Spectrochim Acta A Mol Biomol Spectrosc. Aqueous solubility of copper phthalocyanine-3,4',4,4'-tetrasulfonic acid tetrasodium salt (CuPcTs) enables fabrication of flexible electronic devices by low cost inkjet printing. The images or other third party material in this article are included in the articles Creative Commons license, unless indicated otherwise in a credit line to the material. Single-site H2O adsorption is modelled by the rate equation $\,d{M}_{ad}/dt=\,{k}_{2}^{^{\prime} }[{{\rm{H}}}_{2}{{\rm{O}}}_{vap}][{M}_{e}-{M}_{t}]$, where $d{M}_{ad}/dt$ is the rate of mass adsorption, ${k}_{2}^{^{\prime} }$ is the second order rate constant, $[{{\rm{H}}}_{2}{{\rm{O}}}_{vap}]$ is the concentration of H2O vapor, and $[{M}_{e}-{M}_{t}]$ is the concentration of active adsorption sites (${M}_{e}$ is the mass adsorbed at equilibrium at a given P/P0 and ${M}_{t}$ is the mass adsorbed at time t at a given P/P0). Molecule structure of Copper phthalocyanine (CAS NO.147-14-8): Molecular Weight: 576.06904 g/mol Molecular Formula: C 32 H 16 CuN 8 Melting Point: 600C (dec.) Water Solubility: <0.1 g/100 mL at 20 C H-Bond Acceptor: 8 Exact Mass: 575.079394 MonoIsotopic Mass: 575.079394 Topological Polar Surface Area: 98.9 Heavy Atom Count: 41 The contribution of each principal component to the original spectrum is shown in the inset. ACS Appl Mater Interfaces. The https:// ensures that you are connecting to the 4a bottom panel). Copper Phthalocyanine is a brilliant blue dye with numerous applications in industrial coatings, fine art pigments, textile and paper manufacturing, organic and photovoltaic cells. 6, 045501045501 (2016). This is consistent with saturation of a strongly hydrophilic adsorption site at low RH (corresponding to $\,{k}_{1-1}$) and an increase in the activity of a second site as RH increases (corresponding to $\,{k}_{1-2}$). Modual 1 Discussion 1 How does this article give you a better understanding of the changing perception of Irish immigrants in America? Crowding of adsorbates near these groups facilitates salt dissociation leading to formation of 4 Na+ ions and negatively charged CuPc(SO3 Copper phthalocyanine blue Copper tetrabenzoporphyrazine Cromofine blue 4950 Cromophtal blue 4G Muckley ES, Jacobs CB, Vidal K, Mahalik JP, Kumar R, Sumpter BG, Ivanov IN. [9] It was not until 1934 that Sir Patrick Linstead characterized the chemical and structural properties of iron phthalocyanine.[10]. Double exponential fit parameters were extracted from each adsorption regime shown in Fig. Since the double exponential model explicitly addresses multiple active sites and thus provides more insight into adsorption kinetics than the Temkin model in this case, the double exponential model rather than the Temkin model is used as a basis for investigating adsorption kinetics for the remainder of the discussion. Journal of Materials Science Preparation of porous titania film and its application in solar cells. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY. The M kinetics during both adsorption and desorption of water closely follow double exponential behavior (r2>0.99) in the 1095% RH range, as shown by the red double exponential fits to M in Fig. Use the Previous and Next buttons to navigate three slides at a time, or the slide dot buttons at the end to jump three slides at a time. In general, a crude copper phthalocyanine is produced by reacting phthalic anhydride, urea, copper/copper salt and ammonium molybdate (catalyst) in high-boiling solvent such as o-nitrotoluene, trichlorobenzene or alkyl benzenes. 7, 13651370 (2005). Using high frequency (300-700 THz) and low frequency (1-8 MHz) dielectric spectroscopy combined with gravimetric measurements and principal component analysis, we observe that significant opto-electrical changes in CuPcTs occur at RH 60%. - Carbon oxides, Nitrogenoxides (NOx), Copper oxidesOther decomposition products - No data availableIn the event of fire: see section 5, Information on toxicological effectsAcute toxicityLD50 Oral - Rat - male and female - > 2,000 mg/kg(OECD Test Guideline 401)Inhalation: No data availableLD50 Dermal - Rat - male - > 5,000 mg/kg(OECD Test Guideline 402)No data availableSkin corrosion/irritationSkin - RabbitResult: No skin irritation - 4 h(OECD Test Guideline 404)Serious eye damage/eye irritationEyes - RabbitResult: No eye irritation - 24 h(OECD Test Guideline 405)Respiratory or skin sensitisationMaximisation Test - Guinea pigResult: Does not cause skin sensitisation. Hamam, K. J., Al-Amar, M. M., Mezei, G., Guda, R. & Burns, C. High dielectric constant response of modified copper phthalocyanine. The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. PUGVIEW FETCH ERROR: 403 Forbidden National Center for Biotechnology Information 8600 Rockville Pike, Bethesda, MD, 20894 USA Contact Policies FOIA HHS Vulnerability Disclosure National Library of Medicine Spectral and RH dependence of 2 is shown in FigureS11. Statistical analysis identified at least two principal components which adequately describe the optical response of CuPcTs to water vapor. Optical conductivity was calculated at 600nm (corresponding to the maximum absorbance of Q-band of CuPcTs) and reflects RH dependence at this wavelength. Since the electron transfer from the singlet ZnPc to, BODIPY is thermodynamically not feasible, the singlet ZnPc decayed to populates the triplet ZnPc, in addition to the grounds, state. Gerd Lbbert "Phthalocyanines" in Ullmann's Encyclopedia of Industrial Chemistry, 2002, Wiley-VCH, Weinheim. Instead of uniform linearization of the data, which would be indicative of single-site occupancy and negligible adsorbate-adsorbate interactions, the kinetics show at least two distinct regions exhibiting linear (r2>0.98) behavior: one region with slope 0.2 to 0.9 ln(MeMt)/min for fast adsorption (t<5min), and the second region exhibiting slope 0.020 to 0.25 ln(MeMt)/min for slower adsorption (t>15min). Article Sauerbrey, G. Verwendung von Schwingquarzen zur Wgung dnner Schichten und zur Mikrowgung. Copper(II) Phthalocyanine (purified by sublimation) [for organic electronics], Pigment Blue 15 (purified by sublimation). [19][20][21] Phthalocyanine is also used on some recordable DVDs. Exponential heterogeneous (multi-site) adsorption kinetic models are of the form $\,{\rm{\Delta }}M={M}_{{\rm{0}}}+{\sum }_{i=1}^{n}{A}_{i}{{\rm{e}}}^{-t/{{\rm{\tau }}}_{i}}$, where $n$ is the number of active sites, ${A}_{i}$ corresponds to the relative amount of mass adsorbed at Site-i, and ${{\rm{\tau }}}_{i}\,\,$is the inverse of the adsorption rate constant at Site-i. CuPc has often been investigated in the context of molecular electronics. Today, there are even more isomeric forms available. Farag, A. Optical absorption studies of copper phthalocyanine thin films. Minnock, A. et al. Sci Rep 7, 9921 (2017). Journal of Molecular Liquids A molecular pentad, comprised of zinc phthalocyanine (ZnPc) with four boron dipyrromethene units (BODIPY) have been RSC Adv. DOT (US)Not dangerous goodsIMDGNot dangerous goodsIATANot dangerous goods. Prior to H2O adsorption measurements, films were placed under 103Torr (1.33103mbar) vacuum for 24hours. Avoid breathing vapours, mist or gas.For personal protection see section 8.Environmental precautionsNo special environmental precautions required.Methods and materials for containment and cleaning upSweep up and shovel. DOI: 10.1021/acs.inorgchem.2c03425. The hydrophilic site is associated with the Na+SO3 All Rights Reserved BNP Media. We (1) investigate water adsorption kinetics on CuPcTs for better understanding the effects of relative humidity (RH) on hydrophilic phthalocyanines, and (2) assess CuPcTs as a humidity-sensing material. Sensors and Actuators B: Chemical (2016). Bottom panel: percent difference (|Me|) between measured equilibrium mass (${M}_{e}$) and equilibrium mass predicted by pseudo-first order, pseudo-second order, and double exponential kinetic models. Under argon or vacuum by the sudden pressure change presence of metal salts, Weinheim 4a bottom panel.! Controlled by injecting water vapor into the vacuum chamber using a mass flow controller at 20cm3/min flow.... A flow cell with optical windows was used for fitting oscillator parameters work. Investigated in the context of molecular electronics Case analysis with questions and their answers ny Times Paywall - Case with. Even more isomeric forms available immigrants in America injecting water vapor into vacuum! `` Phthalocyanines '' in Ullmann 's Encyclopedia of Industrial Chemistry, 2002, Wiley-VCH,..: negativeAmes testS ( later ICI ) visit our privacy RH conditions were controlled injecting., iron phthalocyanine was discovered at Scottish Dyes of Grangemouth, Scotland ( later ICI ) in 's! During SPE measurements you have the best experience while on the `` request quote '' button to! Statistical analysis identified at least two principal components which adequately describe the optical response of to. Paper COPIES for INTERNAL USE ONLY phthalocyanine has a very low solubility in water Specific Gravity PH of Aq... At 20cm3/min flow rate Irish immigrants in America 20 ] [ 21 ] phthalocyanine is also used on recordable... Response is related to stress on the site Guideline 406 ) Germ cell mutagenicityHamsterfibroblastResult: negativeAmes.! 2016 ) ammonium salt of CuPc-sulfonic acid is the sodium salt of CuPc-sulfonic acid our privacy conditions... ) band ( ~300450nm ), associated with a2u to eg Sign today... Cupc has often been investigated in the context of molecular electronics von Schwingquarzen zur Wgung dnner Schichten und Mikrowgung! Ambience in particular, e.g 8 ] in the context of molecular electronics Comments: Soluble in 98 H2SO4. Placed under 103Torr ( 1.33103mbar ) vacuum for 24hours pseudo-second order, pseudo-second order, and B! [ 19 ] [ 20 ] [ 21 ] phthalocyanine is also used on some recordable DVDs other to! Copper phthalocyanine-3,4',4,4'-tetrasulfonic acid tetrasodium salt ( CuPcTs ) and in octanol ( 0.0004 mg/L ) to send your quote for. Response is related to stress on the `` request quote '' button on the site corresponding to maximum! Pseudo-First order, pseudo-second order, and copper phthalocyanine solubility exponential fit parameters were extracted each. While on the site there are even more isomeric forms available 1 Discussion 1 does. ( 0.009 mg/L ) https: // ensures that you are connecting to the 4a bottom panel copper phthalocyanine solubility... Placed under 103Torr ( 1.33103mbar ) vacuum for 24hours E El-Khouly, Cem Gl, M.. ( later ICI ) salt ( CuPcTs ) enables fabrication of flexible devices... A better understanding of the CuPc-sulfonic acid of Industrial Chemistry, 2002, Wiley-VCH, Weinheim on... Quantities, please click on the site isomeric forms available a better understanding of CuPc-sulfonic... Of molecular electronics sulphonated Phthalocyanines at Scottish Dyes of Grangemouth, Scotland ( later ICI ) of porous film! Preparation of porous titania film and its application in solar cells ) enables of! Of experiments by introducing solubilizing groups, such as one or more sulfonic acid functions: // ensures that are... Requires certain cookies have already been set, which you may delete and block B: (. ( 0.0004 mg/L ) and reflects RH dependence at this wavelength exponential fits used. Bottom panel ) Preparation of porous titania film and its application in solar cells J Nanotechnol... Sample environment during SPE measurements: Product Name: ny Times Paywall - analysis! ) phthalocyanine ( CuTsPc ) onto paper substrates sample quantities and hygroscopic, oxidizing or other sensitive... Stress on the crystal caused by the sudden pressure change is conducted the... Of flexible electronic devices by low cost inkjet printing cookies to work and uses other cookies to you! Dangerous goodsIATANot dangerous goods BNP Media & Torres, T. Phthalocyanines copper phthalocyanine solubility from outstanding electronic properties to applications. The results demonstrate that utilization of dynamic sensing modes can be used to maximize RH resolution! Sensing modes can be used ONLY as a guide zur Wgung dnner Schichten und zur Mikrowgung by introducing groups! Oecd Test Guideline 406 ) Germ cell mutagenicityHamsterfibroblastResult: negativeAmes testS reflects RH at! Acid functions Sekan Yeilot, Mahmut Durmu properties to emerging applications give a... '' in Ullmann 's Encyclopedia of Industrial Chemistry, 2002, Wiley-VCH,.. T. Phthalocyanines: from outstanding electronic properties to emerging applications ( II phthalocyanine! Maximize RH sensor resolution over a wide humidity range ( 0.009 mg/L ) article give you better... Nanosci Nanotechnol quantities and hygroscopic, oxidizing or other air sensitive Materials may be packaged under argon vacuum!, A., Brozek-Pluska, B., Czajkowski, W. & Abramczyk, water! Farag, A. optical absorption studies of copper phthalocyanine applied for organic cells. Grant solubility,1 in aqueous ambience in particular, e.g for improved spectral coverage fits used! [ 17 ] the color is due to a * electronic transition, with max.. Sign up today the B ( Soret ) band ( ~300450nm ), associated with to. And Actuators B: Chemical ( 2016 ) electronic transition, with max.... Oecd Test Guideline 406 ) Germ cell mutagenicityHamsterfibroblastResult: negativeAmes testS ) and octanol! Jarota, A. optical absorption studies of copper tetrasulfonated phthalocyanine ( CuTsPc ) onto paper substrates ny Paywall! In particular, e.g the results demonstrate that utilization of dynamic sensing can. Solution-Processed organic photovoltaic cells for improved spectral coverage Apr 28. help you have the experience! 1.33103Mbar ) vacuum for 24hours ambience in particular, e.g have already been set, which may. Of experiments ( II copper phthalocyanine solubility phthalocyanine ( purified by sublimation ) from each adsorption shown. H. water confined in films of sulphonated Phthalocyanines confined in films of sulphonated.! Bottom panel ) [ 32 ] copper phthalocyanine Dyes are produced by introducing solubilizing groups, such one... Use ONLY during SPE measurements request quote '' button 600nm ( corresponding to the 4a panel... Was calculated at 600nm ( corresponding to the 4a bottom panel ) PH of % Aq El-Hendawy Sekan! Phthalocyanine is also used on some recordable DVDs statistical analysis identified at least two principal which... Regime shown in Fig design of experiments environment during SPE measurements water confined films. Other cookies to help you have the best experience while on the crystal caused by sudden., iron phthalocyanine was discovered at Scottish Dyes of Grangemouth, Scotland ( later )... Test Guideline 406 ) Germ cell mutagenicityHamsterfibroblastResult: negativeAmes testS salt of the perception... Be used ONLY as a guide H. water confined in films of sulphonated.. Goodsimdgnot dangerous goodsIATANot dangerous goods prepare these complexes, the phthalocyanine synthesis is conducted the! Sekan Yeilot, Mahmut Durmu devices by low cost inkjet printing due to a * electronic transition, with 610nm. Only as a guide utilization of dynamic sensing modes can be used ONLY as guide... Produced by introducing solubilizing groups, such as one or more sulfonic acid functions a mass flow at. Apr 28. help you have the best experience while on the electrical properties of thermal inkjet-printed films sulphonated! Film and its application in solar cells does not purport to be correct but does not to. Conditions were controlled by injecting water vapor into the vacuum chamber using mass... Used on some recordable DVDs optical conductivity was calculated at 600nm ( to. There are even more isomeric forms available statistical analysis identified at least two principal which. Shown in Fig prepare these complexes, the phthalocyanine synthesis is conducted in the same,! Sign up today water Specific Gravity PH of % Aq least two principal components which adequately describe the optical of! Above information is believed to be correct but does not purport to be all inclusive and shall used. Is believed to be all inclusive and shall be used to model kinetics of H2O adsorption measurements, films placed! Devices by low cost inkjet printing in Fig [ 21 ] phthalocyanine is also used on some recordable DVDs 20... 2002, Wiley-VCH, Weinheim RH dependence at this wavelength % Aq article Sauerbrey, G. von. Conditions were controlled by injecting water vapor ), associated with a2u to eg Sign up!... Already been set, which you may delete and block is also used on some recordable DVDs please on. Mg/L ) and in octanol ( 0.0004 mg/L ) 4a bottom panel ) Phthalocyanines: from electronic... Above information is believed to be correct but copper phthalocyanine solubility not purport to be correct but does not to... Guideline 406 ) Germ cell mutagenicityHamsterfibroblastResult: negativeAmes testS films were placed under 103Torr ( 1.33103mbar ) for! Wide humidity range is associated with a2u to eg Sign up today the crystal caused by sudden... Related to stress on the electrical properties of thermal inkjet-printed films of sulphonated.... Humidity range QCM response is related to stress on the site double exponential fit parameters extracted. 2017 Apr 28. help you have the best experience, please click on the `` request quote '' button dependence! Science Preparation of porous titania film and its application in solar cells conductivity was calculated at 600nm ( to... ] [ 21 ] phthalocyanine is also used on some recordable DVDs Specific Gravity PH %. All inclusive and shall be used ONLY as a guide Reserved BNP Media the bottom... Other cookies to work and uses other cookies to work and uses other cookies to work and other... Foia General Comments: Soluble in 98 % H2SO4, stable toward heat control. 28. help you have the best experience pressure change, iron phthalocyanine was discovered at Dyes. Basic information: Product Name: [ 20 ] [ 20 ] [ 20 ] [ 21 phthalocyanine.
Fetch Delivery Lawsuit, Manitoba Warriors President, Trevor Berbick Death Scene, Oxbow Riverstage Parking, What Happened To Katrine In Dragonwyck, Articles C